Every organization has a corporate culture.
It comes from a combination of the industry, the ages of the people who work there, the size of the business, the number of people, the area location and many other factors.
But that culture builds its own work environment, and if employees are not contented with that environment or do not work properly within it, they don’t “fit”. This person will never be an benefit to your company, and may actually leave very quickly.
For this reason you should ask questions whose replies will demonstrate the candidate’s personality and character, their approach towards the workplace.